Formula For Lead Ii Sulfate

Lead(II) sulfate
Names

IUPAC name lead(II) sulfate
Other names Anglesite, fast white, milk white, plumbous sulfate
Identifiers
CAS Number	7446-fourteen-2 ^Y
3D model (JSmol)	Interactive image
ChemSpider	19956579 ^Y
ECHA InfoCard	100.028.362
EC Number	231-198-nine
PubChem CID	24008
UNII	C516H654O8 ^Y
UN number	1759 1794
CompTox Dashboard (EPA)	DTXSID50883502
InChI InChI=1S/H2O4S.Pb.4H/c1-5(ii,iii)four;;;;;/h(H2,1,2,3,4);;;;;/q;+two;;;;/p-2^Y Primal: PIJPYDMVFNTHIP-UHFFFAOYSA-L^Y InChI=1S/H2O4S.Atomic number 82.4H/c1-v(2,three)4;;;;;/h(H2,1,ii,3,iv);;;;;/q;+2;;;;/p-2 Primal: PIJPYDMVFNTHIP-QKXYEYSFAV Key: PIJPYDMVFNTHIP-UHFFFAOYSA-Fifty
SMILES [O-]S(=O)(=O)[O-].[PbH4+ii]
Properties
Chemical formula	PbSO₄
Molar mass	303.26 1000/mol^[1] ^[2]
Advent	white solid
Density	6.29 grand/cmⁱⁱⁱ ^[3]
Melting bespeak	1,087 °C (1,989 °F; 1,360 Thou) decomposes
Solubility in h2o	0.0032 g/100 mL (15 °C) 0.00443 m/100 mL (20 °C)^[iv]
Solubility product (G _sp)	2.13 x x^−eight (20 °C)
Solubility	insoluble in booze soluble in ammonium acetate (≥ half-dozen mol/L) soluble in ammonium tartrate in presence of ammonium chloride and ammonia
Magnetic susceptibility (χ)	−69.7·10^{−half dozen} cm³/mol
Refractive index (north _D)	1.877
Structure
Crystal structure	orthorhombic, barite
Thermochemistry
Oestrus capacity (C)	103 J/degree mol
Std molar entropy (S ^⦵ ₂₉₈)	149 J·mol^−ane·K⁻¹ ^[5]
Std enthalpy of formation (Δ_f H ^⦵ ₂₉₈)	−920 kJ·mol⁻¹ ^[v]
Hazards
GHS labelling:
Pictograms
Indicate word	Danger
Hazard statements	H302, H332, H360Df, H410
Precautionary statements	P201, P202, P260, P261, P264, P270, P271, P273, P281, P301+P312, P304+P312, P304+P340, P308+P313, P312, P314, P330, P391, P405, P501
NFPA 704 (fire diamond)	three 0 0
Flash point	Non-flammable
Threshold limit value (TLV)	0.15 mg/m³
Related compounds
Other anions	Lead(Two) chloride, Lead(2) bromide, Atomic number 82(II) iodide, Lead(Two) fluoride
Other cations	Tin(Ii) sulfate, Sodium sulfate, Copper(2) sulfate
Except where otherwise noted, information are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Northverify (what is^{Y N} ?) Infobox references

Chemical chemical compound

Lead(Ii) sulfate (PbSO_iv) is a white solid, which appears white in microcrystalline form. It is also known as fast white, milk white, sulfuric acid atomic number 82 salt or anglesite.

It is often seen in the plates/electrodes of motorcar batteries, equally it is formed when the battery is discharged (when the battery is recharged, then the lead sulfate is transformed back to metallic atomic number 82 and sulfuric acrid on the negative terminal or atomic number 82 dioxide and sulfuric acrid on the positive terminal). Atomic number 82 sulfate is poorly soluble in water.

Manufacturing [edit]

Atomic number 82(Ii) sulfate is prepared by treating lead oxide, hydroxide or carbonate with warm sulfuric acrid or past treating a soluble lead common salt with sulfuric acid.

Alternatively, it tin be fabricated by the interaction of solutions of atomic number 82 nitrate and sodium sulfate.

Toxicology [edit]

Pb sulfate is toxic past inhalation, ingestion and skin contact. It is a cumulative toxicant, and repeated exposure may lead to anemia, kidney damage, eyesight damage or harm to the key nervous organization (especially in children). It is also corrosive - contact with the eyes can pb to severe irritation or burns. Typical threshold limit value is 0.xv mg/m³.

Mineral [edit]

The naturally occurring mineral anglesite, PbSO₄, occurs every bit an oxidation production of master lead sulfide ore,

Bones and hydrogen pb sulfates [edit]

A number of lead bones sulfates are known: PbSO_iv·PbO; PbSO_four·2PbO; PbSO₄·3PbO; PbSO₄·4PbO. They are used in manufacturing of active paste for lead–acrid batteries. A related mineral is leadhillite, 2PbCO₃·PbSO₄·Pb(OH)₂.

At high concentration of sulfuric acrid (>80%), pb hydrogensulfate, Pb(HSO₄)₂, forms.^[6]

Chemical properties [edit]

Lead(II) sulfate tin can exist dissolved in concentrated HNO₃, HCl, H₂SO_iv producing acidic salts or complex compounds, and in concentrated alkali giving soluble tetrahydroxidoplumbate(Ii) [Pb(OH)_four]²⁻ complexes.

PbSO_four _(s) + H₂Then₄ _(l) ⇌ Pb(HSO₄)₂ _(aq)

PbSO_iv _(s) + 4NaOH_(aq) → Na₂[Atomic number 82(OH)₄]_(aq) + Na₂So_iv _(aq)

Lead(Ii) sulfate decomposes when heated above 1000 °C:

PbSO_four _(southward) → PbO_(s) + SO₃ _(g)

External links [edit]

Case Studies in Environmental Medicine (CSEM): Lead Toxicity
ToxFAQs: Pb
National Pollutant Inventory - Atomic number 82 and Pb Compounds Fact Sheet

References [edit]

^ "Molar Mass of Lead Sulphate". webbook.nist.gov. Archived from the original on 13 December 2020. Retrieved 4 March 2022.
^ "NIST data review 1980" (PDF). National Found of Standards and Engineering (NIST). Archived from the original (PDF) on 21 Dec 2016. Retrieved 4 March 2022.
^ Lide, David R. (14 September 2002). "CRC Handbook of Chemical science and Physics. 83rd Edition". Periodical of the American Chemical Society. National Institute of Standards and Applied science (NIST); CRC Printing: Boca Raton. 124 (47): 14280. doi:10.1021/ja025295q. ISBN9780849304835. ISSN 0002-7863. OCLC 956588069. Archived from the original on 4 March 2022. Retrieved iv March 2022.
^ PubChem. "Lead sulfate". pubchem.ncbi.nlm.nih.gov. Archived from the original on 29 November 2021. Retrieved 2022-03-04 .
^ ^a ^b Zumdahl, Steven S. (2009). Chemical Principles (6th ed.). Houghton Mifflin Visitor. p. A22. ISBN978-0-618-94690-7. OCLC 1029017812.
^ "Министерство образования и науки РФ, Реферат "Свинец и его свойства"" [Abstruse: Lead and its properties]. Ministry of Education and Science of the Russian federation. 2007. Archived from the original on 21 December 2007.